全文获取类型
收费全文 | 832篇 |
免费 | 35篇 |
专业分类
化学 | 742篇 |
晶体学 | 3篇 |
力学 | 4篇 |
数学 | 17篇 |
物理学 | 101篇 |
出版年
2023年 | 8篇 |
2022年 | 4篇 |
2021年 | 6篇 |
2020年 | 11篇 |
2019年 | 18篇 |
2018年 | 11篇 |
2016年 | 14篇 |
2015年 | 16篇 |
2014年 | 11篇 |
2013年 | 39篇 |
2012年 | 46篇 |
2011年 | 58篇 |
2010年 | 23篇 |
2009年 | 30篇 |
2008年 | 56篇 |
2007年 | 64篇 |
2006年 | 50篇 |
2005年 | 54篇 |
2004年 | 53篇 |
2003年 | 40篇 |
2002年 | 39篇 |
2001年 | 14篇 |
2000年 | 6篇 |
1999年 | 9篇 |
1997年 | 7篇 |
1996年 | 7篇 |
1995年 | 6篇 |
1994年 | 6篇 |
1993年 | 6篇 |
1992年 | 10篇 |
1991年 | 10篇 |
1990年 | 8篇 |
1989年 | 8篇 |
1988年 | 7篇 |
1987年 | 4篇 |
1986年 | 7篇 |
1985年 | 10篇 |
1984年 | 4篇 |
1983年 | 6篇 |
1982年 | 11篇 |
1981年 | 7篇 |
1980年 | 12篇 |
1979年 | 7篇 |
1978年 | 8篇 |
1977年 | 6篇 |
1976年 | 3篇 |
1975年 | 4篇 |
1972年 | 4篇 |
1970年 | 3篇 |
1966年 | 3篇 |
排序方式: 共有867条查询结果,搜索用时 203 毫秒
81.
82.
83.
84.
The shielding ability of radiation resistant gloves was examined. The gloves are made of lead loaded (as PbO2) polyvinyl chloride resin and are about 0.4 mm in thickness (70 mg/cm2). Eleven test pieces were sampled from each of three gloves (total 33) and the transmission rates for radiations (X-ray or gamma-ray) through the test pieces were measured with radiation sources, 99mTc, 57Co, 133Ba, 133Xe and 241Am. The differences of the transmission rates for radiations by the positions of the gloves were smaller than 15%, and the differences by three gloves were smaller than 5% in the case of 60 keV and 141 keV radiations. The average transmission rates for radiations in the 33 test pieces were about 40% for 30 keV radiation, about 90% for 80 keV and 140 keV radiations. The shielding characteristic of the gloves is equivalent to about 0.026 mm thick lead plate. 相似文献
85.
A diketone precursor of air-stable bis-2-thienyl-2,6-anthracene was prepared and quantitatively converted to the target acene by photoirradiation of the n-π∗ absorption both in solution and as a film, in air. 相似文献
86.
Tetrabenzoperipentacene: Stable Five‐Electron Donating Ability and a Discrete Triple‐Layered β‐Graphite Form in the Solid State 下载免费PDF全文
Akinobu Matsumoto Dr. Mitsuharu Suzuki Dr. Daiki Kuzuhara Dr. Hironobu Hayashi Prof. Dr. Naoki Aratani Prof. Dr. Hiroko Yamada 《Angewandte Chemie (International ed. in English)》2015,54(28):8175-8178
An oxidative ring‐closure reaction of a tetranaphthylpyrene derivative led to the synthesis of a 56 all‐carbon conjugated tetrabenzoperipentacene. In the single‐crystal X‐ray structure, three molecules make a triple‐layered cluster by π‐stacking, wherein each layer rotates by 120°, and is thus considered a petit β‐graphite. As for the optical properties, the Stokes shift is extremely small (10 cm?1), thus indicating its remarkably rigid framework. The tetrabenzoperipentacene exhibits reversible five‐electron oxidation waves in cyclic voltammetry, and is regarded as a counterpart to the fullerene C60 in terms of stable multicharge‐storage nanocarbon materials. 相似文献
87.
Pyranosides with 2,3-trans carbamate or 2,3-trans carbonate groups are anomerized under mild acidic conditions via endocyclic cleavage reaction. In order to understand the nature of the anomerization reaction via the endocyclic cleavage-recyclization process, the substituent effects at various positions were investigated. 相似文献
88.
Sato T Yoshida S Hoshino H Tanno M Nakajima M Hoshino T 《Journal of the American Chemical Society》2011,133(25):9734-9737
In this study, mono- and pentacyclic C(35) terpenes from Bacillus subtilis were biosynthesized via the cyclization of C(35) isoprenoid using purified enzymes, including the first identified new terpene cyclase that shows no sequence homology to any of the known terpene cyclases. On the basis of these findings, we propose that these C(35) terpenes should be called the new family of "sesquarterpenes." 相似文献
89.
Cyano-bridged bimetal assemblies demonstrate novel magnetic functionalities, particularly Prussian blue analogs, which have unique properties. In this perspective, we describe a charge-transfer phase transition, reversible photomagnetism, second harmonic generation and magnetization-induced second harmonic generation, ferroelectric ferromagnetism, humidity-sensitive magnetism, high ionic conductivity, and a coupling effect (which we named spin-ionics) between ionic conduction and magnetic ordering with Prussian blue analogs. 相似文献
90.
Morohashi N Noji S Nakayama H Kudo Y Tanaka S Kabuto C Hattori T 《Organic letters》2011,13(13):3292-3295
Powdery crystals of p-tert-butylthiacalix[4]arene (2) selectively include EtOH from 1:1 mixtures of MeOH-EtOH and EtOH-PrOH, and EtCO(2)H from HCO(2)H-EtCO(2)H. On the other hand, no acid is included from HCO(2)H-MeCO(2)H, even though MeCO(2)H is included from the neat acid. The origins of these phenomena are discussed based on X-ray analysis of inclusion crystals prepared separately by crystallization. 相似文献